Steam methane reforming posted in chemical process simulation. The hfa is composed of a reforming system including the reformer, gas cleanup system, and peripheral components, a hydrogen compressor, storage tanks, and dispenser. High temperature accelerates the reaction rates of steam methane reforming and carbon dioxide reforming. Recovery of co 2 from units of steam methane reforming at sines refinery alexandre, andre 1,2, alves, sebastiao 1, campos, cristina 2 1department of chemical engineering, instituto superior tecnico, lisbon, portugal. Optimization of a methane autothermal reformingbased.
In the overall steam methane reforming smr reaction, methane reacts with steam at high temperatures and moderate pressures in catalystfilled tubes to generate synthesis gas, a mixture of hydrogen, carbon monoxide and some carbon dioxide. Simulation, sensitivity analysis and optimization of hydrogen production by steam reforming of methane using aspen plus. Combined steam reforming and partial oxidation of methane to synthesis gas under electrical discharge korada supat and sumaeth chavadej the petroleum and petrochemical college, chulalongkorn university, bangkok 10330, thailand. Conventional steam reforming with co capture has been used as a base case for. Introduction to dynamic process simulation using aspen hysys v10 with a worked example duration. Within such a context, this work evaluates the technical performance of a novel cmr, which utilizes two catalysts in series, rather than one. Jul 28, 20 steam reforming the basics of reforming 1. Hysys conversion coefficient for multiple reactions. Methane steam reforming pdf document methane steam reforming. Results showed that carbon dioxide reforming of methane to synga. This document entitled chemical process simulation and the aspen hysys v8.
Hydrogen production by steam reforming chemical engineering. Steam methane reforming of natural gas or naphtha is the most widely used process for commercial production of hydrogen. Hydrogen is predominantly generated from the reaction amongst methane and steam. The resultants of the reaction include hydrogen, carbon monoxide and a relatively small amount of carbon dioxide. Methane is a potent greenhouse gas that is contributing to climate change. Reducing emissions of both methane and carbon dioxide is. Chemical reactions catalyst shape design catalyst chemistry carbon formation and removal 3. The reactions for the two simultaneous smr mechanisms are shown as equations 1 and 2. For the baseline hfa, we compared the costs and efficiencies of two hydrogengeneration technologies steam methane reforming and autothermal reforming and two hydrogen purification.
Technoeconomic analysis tea for co 2 reforming of methane in a membrane reactor mr was conducted by using process simulation and economic analysis. Kinetic based simulation of methane steam reforming and. Relationship between the oxygen available in the solid for methane reforming and the oxygen release rate during methane reforming to achieve the treatment of 1500 tch 4 day with a 10 m. Journal of the taiwan institute of chemical engineers. With the reaction kinetics for msr reported by xu and. Smr based plants are most commonly used to produce a hydrogen product or a combination of a hydrogen stream and. Simulation of hydrogen production for mobile fuel cell applications via autothermal reforming of methane. This chapter describes the process and steadystate simulation of the methane. Combined steam reforming and partial oxidation of methane to.
Pdf kinetic based simulation of methane steam reforming. The scale of the modeling within section 2 is based on a steam methane reforming smr process that produces 719 tonsday of hydrogen. The pengrobinson fluid package was chosen for use in the hysys simulation because it is ideal for describing hydrocarbon systems such as the steam methane reforming plant, where most components are gases or are nonpolar. This manual is intended as a guide to using aspentechs software. Carbon dioxide reforming of methane to produce synthesis gas over metalsupported catalysts. Experiential learning and working with students in the labs 6. H298k 75 kjmol ch4 several parameters have been defined, including dimensions and information on the porous medium. Select ethylbenzene from the drop down list in the edit bar. Water enters the furnace, producing steam at a very high temperature. This paper presents the kineticbased simulation of methane steam reforming msr from natural gas and water gas shift wgs reaction for hydrogen. Most of the methane conversion had been achieved in the half of the catalyst bed. Sep 19, 2016 palladiumbased catalytic membrane reactors cmrs effectively remove h 2 to induce higher conversions in methane steam reforming msr and watergasshift reactions wgs.
The good news is, you can use the case study tool in hysys to generate these numbers and still make your tee time. Science confirms methane is a problem that requires urgent attention. None of the commercial process simulators aspen plus, proii, hysys, etc. Nov 11, 2014 dry reforming of methane in a dielectric barrier discharge reactor with nial 2 o 3 catalyst. Methane and carbon dioxide are major feedstocks of an autothermal reformer atr and a co2 reformer, respectively.
Learn aspen plus in 24 hours integrating aspen plus into the chemical engineering classroom. Aug 28, 2014 the much lower cost of natural gas and the desire to reduce carbon dioxide emissions have stimulated interest in the dry methane reforming process in which these two gases react to produce synthesis gas. This site is like a library, use search box in the widget to get ebook that you want. Kinetic based simulation of methane steam reforming and water gas shift for hydrogen production using aspen plus article pdf available in chemical engineering transactions 56. Natural gas is sent to the primary reformer for steam.
Please guide me with the techniques used and references available. Please check your email for instructions on resetting your password. I do not own this song all credit goes to the writer and the band. Simulation, sensitivity analysis and optimization of.
Using hysys, you can model and simulate the steam ethane reforming with propylene. This is largely due to its cost effectivness in obtaining a high level of purity in its produced hydrogen. Uops polybed psa system produces the highpurity hydrogen needed for the optimum performance of catalytic processes. Steam methane reforming is the most common and economical way to make hydrogen. Reforming unit the main reaction occurring in the reformer is the conversion of methane to a mixture of co, co2 and h2. The models included all the feed pretreatment steps along with the reforming reactors and effluent treatment. The 16 study series an unprecedented look at methane from the natural gas system methane ch4 is a growing environmental concern. Analysis of hydrogen production from methane autothermal. The purpose of hses assessment of a safety report against the criteria in the sram, is to come to a conclusion on whether the requirements and demonstrations in schedule 4 part 1 have been met. Reformer modelbased inferential properties embedded in apc.
Carbon dioxide reforming of methane to syngas by thermal plasma. Steam methane reforming is the most widely used process for bulk gas production, accounting for 95% of the hydrogen produced in the united states. This reforming process operates at very high severity where the reaction temperatures are in the range of 850950 deg c. Pdf simulation of hydrogen production for mobile fuel. Pdf assessments for lowtemperature methane reforming. If anyone is working with modelling of steam methane reforming with. Process assessments for lowtemperature methane reforming. Methane steam reforming reaction behaviour in a packed bed. Figure 2 fuel processor plant developed using aspen hysys 2004. Steam reforming of natural gas wikid energy funhouse. Monitor the effect of molar flow of steam multiplier of 1. Algorithm for methane number determination for natural gasses. Because hydrogen needs within various sectors of the cpi are at their highest levels in history, and are continuing to grow, an understanding of this method of hydrogen production and purification can be useful. Simulation, sensitivity analysis and optimization of hydrogen production by.
Methane is almost completely consumed at inlet conditions of the catalyst bed due to the high temperature of gases coming from the combustion zone. The autothermal reforming of methane developed using hysys 2006. Methane steam reforming reaction behaviour in a packed bed membrane reactor lemnouer chibane and brahim djellouli international journal of chemical engineering and applications, vol. Steam reforming of light hydrocarbons, such as natural gas, is the dominant technology for the production of syngas, and thus, of hydrogen. Different technologies are available to produce syngas from natural gas including catalytic steam methane reforming smr, twostep reforming. Hysys conversion coefficient for multiple reactions posted in chemical process simulation. May 14, 2010 steammethane reforming is a process in which high temperature steam 700c c is reacted with a methane source usually natural gas at a high pressure of 325 bar with a catylist. Dear claud, im intersted in steam reforming as well. Methane steam reforming, methanation and watergas shift.
The formulaes developed to calculate the methane number are based on the assumption that the methane number curves in figure 2. Pdf kinetic based simulation of methane steam reforming and. Stabilize steam methane reformer combustion, reduce variability, and gain control of energy costs with emersons steam methane reformer solution, which will enable your operators to respond to changing conditions, keep your equipment from degrading and failing, and help stabilize your reformers performance. The aspen hysys software used for the simulation conducted here does not. The simulation results show that the dualbed autothermal.
The various hydrogen production schemes were investigated for three different fuels. C2pt catalyst process technology by gerard b hawkins managing director 2. Modeling and simulation of an industrial secondary reformer. Then select the conversion reaction refer to section 4. The design of the steam reforming process is in part dictated by these constraints. Jul 19, 2012 methane is almost completely consumed at inlet conditions of the catalyst bed due to the high temperature of gases coming from the combustion zone. This documentation contains aspentech proprietary and. On the stoichiometry tab add all of the components to the.
The autothermal reforming of methane developed using hysys 2004. It is reversible and strongly endothermic, and according to the principle of le chatelier it must be carried out at high temperature, high steam to methane ratio, and low pressure to achieve maximum conversion. Pdf optimization of a methane autothermal reforming. Pdf simulation, sensitivity analysis and optimization of. The waste heat recovery technique is applied to build a standalone ideal heatintegrated system. Review on dry reforming of methane, a potentially more. Process simulation to obtain a synthesis gas with high concentration of hydrogen 31 the addition of steam in the second reactor serves to the dual purpose of maintaining the reactor temperature and either to ensure that the excess of methane from the natural gas stream is consumed. Steam methane reforming steam power plants nuclear power systems hydrogen production. Onsite hydrogen generation by steam methane reforming what its like to be a. The first section of ptal2o3 catalyst is designed for oxidation reaction, whereas the second one based on nimgal2o4 catalyst involves steam reforming reaction. Reformer modelbased inferential properties embedded in apc page 4 rigorous model the aspen hysys reformer model is based on fundamental kinetics and its integrated with hysys fractionationheat exchange models providing this way a full flowsheet model which is represented in the figure below.
Open a new case by clicking on the blank white page or use the commands file new. Post jobs, find pros, and collaborate commissionfree in our professional marketplace. The main reactions associated with the steam methane reforming process. Additional information on hysys thermodynamics packages can be found in the simulation basis manual appendix a. Aspen hysys 2006 provides tool to design a steady and dynamics state. Hydrogen from natural gas via steam methane reforming smr. Simulation of hydrogen production for mobile fuel cell. Pdf methane steam reforming has been simulated, analyzed and optimized with the aid of aspen plus, in this work. Reforming, catalytic cracking, hydrocracking hydrocracking severe form of hydroprocessing break carbon. Chemical process simulation and the aspen hysys v8. On the stoichiometry tab select the first row of the component column in stoichiometry info matrix. Overview of the book learn aspen plus in 24 hours 3. Process design simulation of h2 production by sorption enhanced.
In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted with nickel catalyst to produce hydrogen h. Autothermal reforming atr technology was used for the production of the synthesis gas since it is one of the best ways of producing methanol in large capacities. Cost and performance comparison of stationary hydrogen. Click download or read online button to get aspen hysys book now. Methane steam reforming reaction behaviour in a packed.
The steam methane reforming process can be broken down into five distinct steps. Page 1 steam reforming of natural gas at petroleum refining facilities is the predominant means of producing hydrogen in the chemical process industries cpi. Normally, natural gasses contain methane, ethane, propane, butane, pentane. This paper presents a performance analysis of a dualbed autothermal reformer for hydrogen production from methane using a nonisothermal, one dimensional reactor model. Kinetics, catalysis and mechanism of methane steam reforming. Design and evaluation of a heatintegrated hydrogen. Steam methane reforming, or smr, processes feedstocks, ranging from natural gas to light naphtha, mixed with steam to produce a hydrogen rich syngas effluent, with a typical h 2 co ratio of 3. This paper presents the kineticbased simulation of methane steam reforming msr from natural gas and water gas shift wgs reaction for hydrogen production. Design and evaluation of a heatintegrated hydrogen production system by reforming methane and carbon dioxide. A large number of detailed reaction mechanisms were considered. Simulation of hydrogen production for mobile fuel cell applications.
Design and control of the dry methane reforming process. The methanol synthesis part which is of importance. Steam methane reforming chemical process simulation. Parametric studies for key operating conditions like a h 2 permeance, a h 2 o sweep gas flow rate, operating temperature, and a co 2 ch 4 ratio were carried out for a conventional packedbed reactor pbr and a mr using aspen hysys, a. Steam methane reforming hydrogen production hysys tutorial. May 19, 2011 introduction to dynamic process simulation using aspen hysys v10 with a worked example duration. It represents the eiga contribution to the refineries bref1 being organized by the european ippc2 bureau. Modeling and simulation of an industrial secondary. Kinetic based simulation of methane steam reforming and water. Comparison of exergy losses for reformers involved in hydrogen. Steam reforming sr is more and more studied to produce.
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